English | 2021 | ISBN: 3527348573 | 416 pages | True PDF | 14.01 MB
Exploresthe potential ofnew types ofanion-binding catalyststo solve challenging synthetic problems
Anion-Binding Catalysisintroduces readers totheuse ofanion-binding processesincatalytic chemical activation, exploring how this approach can contribute to thefuture design ofnovelsynthetic transformations.Featuring contributions byworld-renownedscientistsinthe field, thisauthoritativevolumedescribesthestructure, properties,and catalytic applicationsofanionsas well as synthetic applications and practical analytical methods.
In-depth chaptersare organized by type of catalystratherthanreaction type, providingreaders with an accessibleoverviewofthe existing classes of effective catalysts.The authors discusstheuse of halogens as counteranions,the combination of(thio)urea and squaramide-basedanion-binding with other typesof organocatalysis,anion-binding catalysis by pnictogen and tetrel bonding,nucleophilic co-catalysis, anion-binding catalysis by pnictogen and tetrel bonding,and more.Helpingreadersappreciateandevaluatethe potential of anion-binding catalysis, this timely book:
Illustratesthe historical development, activationmode,and importance of anion-binding in chemical catalysisExplains theanalytic methodsused todeterminethe anion-binding affinity of the catalystsDescribescatalytic and synthetic applicationsof commonNH-and OH-basedhydrogen-donor catalystsas well asC-H triazole/triazolium catalystsCoversamino-catalysis involving enamine, dienamine, or iminium activation approachesDiscusses newtrendsin the field of anion-binding catalysis,such asthe combination of anion-binding with other types of catalysis
Presenting thecurrentstate of thefieldas well as the synthetic potential of anion-binding catalysis in future,Anion-Binding Catalysisis essential reading forresearchers in both academia and industry involved inorganic synthesis, homogeneous catalysis,andpharmaceutical chemistry.